Setup
With
$$ T=\inf\{t\ge 0:B_t=-a \text{ or } B_t=b\}, $$we want $\mathbb E[T]$.
Martingale used
Use the martingale
$$ B_t^2-t. $$Applying OST gives
$$ \mathbb E[B_T^2-T]=0, $$so
$$ \mathbb E[T]=\mathbb E[B_T^2]. $$Compute the value
Using the exit probabilities,
$$ \mathbb E[B_T^2]
b^2\cdot \frac{a}{a+b} + a^2\cdot \frac{b}{a+b} =ab. $$
Therefore
$$ \mathbb E[T]=ab. $$